He bets $25, so you can win $125 by paying $25. You have 9 outs out of 46 unseen cards.
That part is worth 0.196 × $125, or +$24.46.
You lose your $25. That part is worth −$20.11.
Add them up. Every time you make this call, it earns $4.35 on average, and you'll still lose it four times out of five.